Transition Metal Oxides Structure, Properties, and Synthesis of Ceramic Oxides,9780471189718

Transition Metal Oxides Structure, Properties, and Synthesis of Ceramic Oxides

by ;
Edition: 2nd
ISBN13: 9780471189718
ISBN10: 0471189715
Format: Hardcover
Pub. Date: 1998-03-13
Publisher(s): Wiley-Interscience
List Price: $365.25

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Summary

Praise for the First Edition: "Very useful for researchers in solid-state chemistry and as a textbook of advanced inorganic chemistry for PhD students." -Advanced Materials. This book provides unified coverage of the structure, properties, and synthesis of transition metal oxides. Written by two world-class scientists, it offers both an excellent window on modern solid-state chemistry and a gateway to understanding the behavior of inorganic solids. Scientists and advanced students in inorganic and solid-state chemistry, materials science, ceramics, and condensed matter science will welcome this updated Second Edition, which features new or expanded material on: * Oxyanion derivatives of cuprates, mercury cuprates, ladder compounds, and new oxide systems * Giant magnetoresistance, superconductivity, and nonlinear materials * Recently developed synthetic strategies and examples, including soft chemistry routes Plus: * Hundreds of illustrations * Helpful references.

Author Biography

C. N. R. RAO is Albert Einstein Research Professor at the CSIR Centre of Excellence in Chemistry at the Indian Institute of Science and Jawaharlal Nehru Centre for Advanced Scientific Research in Bangalore, India.<br> <br> EAU is Professor at the Laboratoire CRISMAT, Centre des MatTriaux Supraconducteurs in Caen, France.

Table of Contents

Preface to the Second Edition vii(2)
Preface ix
Part I Structure 1(226)
1 Introduction
3(1)
2 Basic Background Material
4(25)
2.1 Description of Crystalline Oxides
4(9)
2.2 Defects in Oxides
13(8)
2.3 Characterization Techniques
21(6)
2.4 Phase Transitions
27(2)
3 Mother Structures of Some Binary Transition Metal Oxides
29(9)
4 Perovskites and Relatives
38(52)
4.1 Stoichiometric Perovskites, ABO(3)
38(4)
4.2 Nonstoichiometric Perovskites, A(x)BO(3)
42(4)
4.3 Oxygen-Deficient Perovskites
46(13)
4.4 Close-Packed Structures Derived from the Perovskites
59(2)
4.5 Intergrowths of Perovskites with Other Structures
61(14)
4.6 Shearlike Phenomena and Introduction of Pillars in the Perovskite Structure
75(4)
4.7 Adaptability of the ReO(3)-Type Framework with PO(4) Tetrahedra: The Phosphate Tungsten Bronzes
79(6)
4.8 Introduction of Carbonate and Other Oxyanions in the Perovskite Structure
85(5)
5 Octahedral Tunnel Structures: Bronzes and Bronzoids
90(19)
5.1 Tunnel Structures with Angles of 90 Degree
90(4)
5.2 Tunnel Structures with Angles of 60 Degree - 120 Degree
94(5)
5.3 Structures with Pentagonal Tunnels
99(9)
5.4 Other Examples of Octahedral Structures with Large Tunnels
108(1)
6 Octahedral Intersecting Tunnel Structures: Pyrochlores and Relatives
109(9)
6.1 Pyrochlores
110(3)
6.2 A(2)B(7)O(18) Oxides
113(1)
6.3 Pyrochlore Intergrowths: HTB-A(2)B(7)O(18)
114(2)
6.4 K(5)Sb(4)O(11) and K(3)Sb(5)O(14)
116(2)
7 Octahedral Lamellar Oxides
118(17)
7.1 Niobates and Titanates of the Formula A(n)B(n)O(3n+2) and Molybdates of the Type Cs(2)Mo(n)O(3n+1) Derived from the Perovskite Structure
118(1)
7.2 Lamellar Structures Built up of Edge-Sharing Octahedra
119(16)
8 Close-Packed Oxides: Spinels, Hexagonal Ferrites, and Relatives
135(18)
8.1 Close-Packed and Pseudo-Close-Packed B(2)O(4) Oxides
135(8)
8.2 Close-Packed B(5)O(8) Oxides: Relationship with the DH LiFeSnO(4) Structure
143(6)
8.3 Hexagonal Ferrites: Relationship with Close-Packed B(5)O(8) and B(3)O(4) Oxides
149(4)
9 Three-Dimensional Mixed Frameworks Involving Tetrahedra and Octahedra
153(38)
9.1 Silicates and Germanates
153(9)
9.2 Phosphates
162(25)
9.3 Other Examples of Mixed Frameworks of Octahedra and Tetrahedra
187(4)
10 Examples of Unusual Coordination: The Vanadium Oxides
191(3)
11 Shear Structures
194(11)
11.1 Shear Structures in Rutile-Type Oxides
194(1)
11.2 Shear Structures in ReO(3)-Type Oxides
195(10)
12 The Highly Complex Structural Behavior of Transition Metal Oxides
205(15)
12.1 Modulated Structures
206(2)
12.2 Extended Defects and Order-Disorder Phenomena
208(5)
12.3 Phasoids
213(2)
12.4 Infinitely Adaptive Structures
215(5)
References
220(7)
Part II Properties and Phenomena 227(96)
1 Introduction
229(1)
2 Electrons in Transition Metal Oxides
230(10)
2.1 Band Model
230(5)
2.2 Localized Electron Model
235(1)
2.3 Cluster Model
236(1)
2.4 Chemical Bond Approach
236(4)
3 Properties of Oxide Materials
240(11)
3.1 Magnetic Properties
241(3)
3.2 Electrical Properties
244(4)
3.3 Superconductivity
248(1)
3.4 Dielectric and Optical Properties
249(2)
4 Electronic and Magnetic Properties of Oxides in Relation to Structure
251(10)
4.1 Monoxides
252(2)
4.2 Dioxides
254(2)
4.3 Sesquioxides
256(1)
4.4 Perovskites and Spinels
257(4)
5 Mixed Valence
261(2)
6 Metal-Nonmetal Transitions
263(6)
7 Low-Dimensional Oxides
269(1)
8 Superconducting Oxides
270(13)
9 Ferroics
283(5)
10 Results from Empirical Theory
288(4)
11 Understanding Electronic Structures from Electron Spectroscopy Combined with Empirical Theory
292(8)
12 Giant Magnetoresistance and Related Aspects
300(14)
12.1 Unique Features of Rare-Earth Manganates
301(4)
12.2 Magnetotransport Properties and GMR
305(2)
12.3 Charge versus Spin Ordering
307(5)
12.4 Tl(2)Mn(2)O(7) and La(l-x)A(x)CoO(3)
312(1)
12.5 Concluding Remarks
313(1)
13 Nanomaterials
314(1)
14 Catalysts and Gas Sensors
315(3)
References
318(5)
Part III Preparation of Materials 323(42)
1 Introduction
325(2)
2 Typical Reactions
327(1)
3 Ceramic Preparations
328(2)
4 Use of Precursors
330(5)
5 Topochemical and Intercalation Reactions
335(6)
6 Ion Exchange Method
341(1)
7 Alkali Flux and Electrochemical Methods
342(2)
8 Sol-Gel Method
344(1)
9 Reactions at High Pressures
345(3)
10 Superconducting Cuprates
348(2)
11 Arc and Skull Techniques
350(2)
12 Soft Chemical Routes
352(1)
13 Crystal Growth
353(5)
14 Concluding Remarks
358(2)
References
360(5)
Index 365

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