Qualitative Analysis and the Properties of the Ions in Aqueous Solutions

by ;
Edition: 1st
Format: Paperback
Pub. Date: 1990-01-02
Publisher(s): Cengage Learning
List Price: $172.81

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Summary

This inexpensive qualitative analysis supplement offers maximum flexibility and can accompany general chemistry texts. Works well with any general chemistry text, where the instructor wants more qualitative analysis in conjunction with regular class work.

Table of Contents

The Theory and Practice of Qualitative Analysis
1(21)
The General Method in Qualitative Analysis
2(2)
The Law of Chemical Equilibrium
4(1)
Precipitation Reactions
5(4)
Acid--Base Reactions
9(7)
Complex Ion Formation---Amphoterism
16(3)
Oxidation-Reduction Reactions
19(3)
Laboratory Procedures
22(8)
Equipment Used in Semimicro Analysis
22(1)
Common Laboratory Operations
23(4)
Safety in the Laboratory
27(1)
Disposal of Reaction Products
28(1)
General Suggestions
28(2)
The Cations
30(73)
A Brief Introduction
30(2)
The Properties of the Cations in Group l---Ag+, Pb2+, Hg2 2+
32(1)
Silver, Ag+
32(1)
Lead, Pb2+
33(2)
Mercury (I), Hg2 2+
35(2)
Analysis of the Group I Cations
37(1)
General Discussion
37(1)
Procedure for Analysis
38(6)
The Properties of the Cations in Group II---Cu2+, Bi3+, Hg2+, Cd2+, (Pb2+), Sn2+ and Sn4+, Sb3+, and Sb5+
44(1)
Copper, Cu2+
44(1)
Bismuth, Bi3+
45(2)
Mercury (II), Hg2+
47(1)
Cadmium, Cd2+
47(1)
Tin, Sn2+ and Sn4+
48(1)
Antimony, Sb3+ and Sb5+
49(2)
Analysis of the Group II Cations
51(1)
General Discussion
51(1)
Procedure for Analysis
52(13)
The Properties of the Cations in Group III---Fe2+ and Fe3+, Al3+, Zn2+, Mn2+, Cr3+, Co2+, Ni2+
65(1)
Iron, Fe2+ and Fe3+
65(1)
Aluminum, Al3+
66(1)
Zinc, Zn2+
67(1)
Manganese, Mn2+
68(2)
Chromium, Al3+
70(1)
Cobalt, Co2+
71(2)
Nickel, Ni2+
73(2)
Analysis of the Group III Cations
75(1)
General Discussion
75(1)
Procedure for Analysis
76(11)
The Properties of the Cations in Group IV---Ba2+, Ca2+, Mg2+, Na+, K+, NH4 +
87(1)
Barium, Ba2+
87(1)
Calcium, Ca2+
88(1)
Magnesium, Mg2+
89(1)
Ammonium, NH4+
90(1)
Sodium, Na+
91(1)
Potassium, K+
91(2)
Analysis of the Group IV Cations
93(1)
General Discussion
93(1)
Procedure for Analysis
94(9)
The Anions
103(43)
A Brief Introduction
103(9)
Preliminary Tests for Analysis of Anions---CO3 2-, CrO4 2-, PO4 3-, SO3 2-, CI-, Br-, SCN-, S2-, NO3-, NO2-, CIO3-, C2H3O2-
105(7)
The Properties of the Anions in the Sulfate Group---CO3 2-, SO4 2-, CrO4 2-, PO4 3-, C2O4 2-, SO3 2-
112(1)
Carbonate, CO3 2-
112(1)
Sulfate, SO4 2-
113(1)
Chromate, CrO4 2-
114(1)
Phosphate, PO4 3-
115(1)
Sulfite, SO3 2-
116(1)
Oxalate, C2O4 2-
117(7)
Procedure for Analysis of Anions in the Sulfate Group
118(6)
The Properties of the Anions in the Chloride Group---CI-, Br-, I-, SCN-, S2-
124(1)
Chloride, Cl-
124(1)
Bromide, Br-
125(1)
Iodide, I-
126(1)
Thiocyanate, SCN-
127(1)
Sulfide, I-
128(8)
Procedure for Analysis of Anions in the Chloride Group
129(7)
The Properties of the Anions in the Nitrate Group---NO3-, NO2-, C2H3O2-, CIO3-
136(1)
Nitrate, NO3-
136(1)
Nitrite, NO2-
137(1)
Chlorate, CIO3-
138(1)
Acetate, C2H3O2-
139(7)
Procedure for Analysis of Anions in the Nitrate Group
141(5)
Identification of a Pure Ionic Compound
146(37)
Introduction
146(3)
Procedure for Analysis
149(8)
Appendix I
Some Anion--Anion Reactions
157(1)
Some Stable Complex Ions
Appendix II
Summary of Solubility Properties of Ions and Solids
158(3)
Appendix III
Answers to Problems
161(13)
Appendix IV
Preparation of Reagents
174(4)
Appendix V
Disposal of Chemical Wastes
178(5)
Index 183

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