Progress in Inorganic Chemistry, Volume 36,

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Format: eBook
Pub. Date: 2009-09-01
Publisher(s): Wiley-Interscience
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Table of Contents

Early Observations Of Interactions Between C-H Bonds And Transition Metal Centers
Classification Of Compounds With Agostic Bonds
General Physical And Chemical Properties
Structural Determinations Using X-Ray, Neutron, and Electron Diffraction Techniques
Nuclear Magnetic Resonance Studies
Infrared Spectroscopy
The Nature Of Agostic Bonding
General Considerations Concerning Three-Center, Two-Electron Bonds
The Representation of Agostic Bonds: The Half-Arrow Convention
Theoretical Discussions of Molecules Containing Distortions at the ¿-Carbon Atom: Distorted Methyl Groups and Distorted Alkylidene Ligands
Compounds Containing Agostic M-H-C Groups
Agostic Alkyls
Agostic Alkylidene Compounds
Agostic Compounds Involving Unsaturated Hydrocarbon Ligands
Compounds Containing Metal-Hydrogen-M' Bridges Where M' = B, N, Si, Cl, F. Metal-Hydrogen-Boron-Bridges
Three Center, Two-Electron Bonding in the M-H-Si System
Metal-Hydrogen-Nitrogen Bridges
Miscellaneous Agostic Systems
Implications Of Agostic Interactions In Transition Metal Catalyzed Reactions Of Hydrocarbons
General Observations
ConclusionS
References
Table of Contents provided by Publisher. All Rights Reserved.

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